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Pn arrivals from mining-induced earthquakes on the edge of the Witwatersrand basin show that the P wavespeeds in the uppermost mantle are almost constant throughout most of the Kaapvaal craton. The presence of only small wavespeed variations allows the use of a simple method of estimating crustal thicknesses below the stations of the Kaapvaal broad-band network using Pn times that has been compared with results from receiver functions. One thousand three hundred thirty-seven Pn arrivals were used to derive crustal thicknesses at 46 stations on the Kaapvaal craton. The average crustal thicknesses for 19 centrally located stations on each of the northern and southern regions of the craton that yielded well-constrained thicknesses were 50.52±0.88 km and 38.07±0.85 km, respectively. In contrast, the corresponding average thicknesses determined from receiver functions were 43.58±0.57 km and 37.58±0.70 km, respectively. The systematically lower values for receiver functions in the northern part of the Kaapvaal craton that was affected by the Bushveld magmatism at 2.05 Ga, suggest that the receiver functions do not enable the petrological crust mantle boundary to be reliably resolved due to variations in composition and metamorphic grade in a mafic lower crust. The Pn times also suggest pervasive azimuthal anisotropy with maximum wavespeeds of about 8.40 km/s at azimuths of about 15° and 217° in the northern and southern regions of the craton, respectively, and minimum wavespeeds of about 8.25 km/s.  相似文献   
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Interatomic potential parameters have been derived at simulated temperatures of 0 K and 300 K to model pyrite FeS2. The predicted pyrite structures are within 1% of those determined experimentally, while the calculated bulk modulus is within 7%. The model is also able to simulate the properties of marcasite, even though no data for this phase were included in the fitting procedure. There is almost no difference in results obtained for pyrite using the two potential sets; however, when used to model FeS2 marcasite, the potential fitted at 0 K performs better. The potentials have also been used to study the high-pressure behaviour of pyrite up to 44 GPa. The calculated equation of state gives good agreement with experiment and shows that the Fe–S bonds shorten more rapidly that the S–S dimer bonds. The behaviour of marcasite at high pressure is found to be similar to that of pyrite.  相似文献   
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The CUTLASS Finland HF radar has been operated in conjunction with the EISCAT Tromsø RF ionospheric heater facility to examine a ULF wave characteristic of the development of a field line resonance (FLR) driven by a cavity mode caused by a magnetospheric impulse. When the heater is on, striating the ionosphere with field-aligned ionospheric electron density irregularities, a large enough radar target is generated to allow post-integration over only 1 second. When combined with 15 km range gates, this gives radar measurements of a naturally occurring ULF wave at a far better temporal and spatial resolution than has been achieved previously. The time-dependent signature of the ULF wave has been examined as it evolves from a large-scale cavity resonance, through a transient where the wave period was latitude-dependent and the oscillation had the characteristics of freely ringing field lines, and finally to a very narrow, small-scale local field line resonance. The resonance width of the FLR is only 60 km and this is compared with previous observations and theory. The FLR wave signature is strongly attenuated in the ground magnetometer data. The characterisation of the impulse driven FLR was only achieved very crudely with the ground magnetometer data and, in fact, an accurate determination of the properties of the cavity and field line resonant systems challenges the currently available limitations of ionospheric radar techniques. The combination of the latest ionospheric radars and facilities such as the Tromsø ionospheric heater can result in a powerful new tool for geophysical research.  相似文献   
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Questions persist about interpreting isotope ratios of bound and mobile soil water pools, particularly relative to clay content and extraction conditions. Interactions between pools and resulting extracted water isotope composition are presumably related to soil texture, yet few studies have manipulated the bound pool to understand its influence on soil water processes. Using a series of drying and spiking experiments, we effectively labelled bound and mobile water pools in soils with varying clay content. Soils were first vacuum dried to remove residual water, which was then replaced with heavy isotope-enriched water prior to oven drying and spiking with heavy isotope-depleted water. Water was extracted via centrifugation or cryogenic vacuum distillation (at four temperatures) and analysed for oxygen and hydrogen isotope ratios via isotope ratio mass spectrometry. Water from centrifuged samples fell along a mixing line between the two added waters but was more enriched in heavy isotopes than the depleted label, demonstrating that despite oven drying, a residual pool remains and mixes with the mobile water. Soils with higher clay + silt content appeared to have a larger bound pool. Water from vacuum distillation samples have a significant temperature effect, with high temperature extractions yielding progressively more heavy isotope-enriched values, suggesting that Rayleigh fractionation occurred at low temperatures in the vacuum line. By distinctly labelling bound and mobile soil water pools, we detected interactions between the two that were dependent on soil texture. Although neither extraction method appeared to completely extract the combined bound and mobile (total water) pool, centrifugation and high temperature cryogenic vacuum distillations were comparable for both δ2H and δ18O of soil water isotope ratios.  相似文献   
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